| 1 | package Post
|
|---|
| 2 | package Chemsep_Database
|
|---|
| 3 | model General_Properties
|
|---|
| 4 | parameter Integer SN;
|
|---|
| 5 | parameter String name;
|
|---|
| 6 | parameter Real Tc;
|
|---|
| 7 | parameter Real Pc;
|
|---|
| 8 | parameter Real Vc;
|
|---|
| 9 | parameter Real Cc;
|
|---|
| 10 | parameter Real Tb;
|
|---|
| 11 | parameter Real Tm;
|
|---|
| 12 | parameter Real TT;
|
|---|
| 13 | parameter Real TP;
|
|---|
| 14 | parameter Real MW;
|
|---|
| 15 | parameter Real LVB;
|
|---|
| 16 | parameter Real AF;
|
|---|
| 17 | parameter Real SP;
|
|---|
| 18 | parameter Real DM;
|
|---|
| 19 | parameter Real SH;
|
|---|
| 20 | parameter Real IGHF;
|
|---|
| 21 | parameter Real GEF;
|
|---|
| 22 | parameter Real AS;
|
|---|
| 23 | parameter Real HFMP;
|
|---|
| 24 | parameter Real HOC;
|
|---|
| 25 | parameter Real UniquacR;
|
|---|
| 26 | parameter Real UniquacQ;
|
|---|
| 27 | parameter Real LiqDen[6];
|
|---|
| 28 | parameter Real VP[6];
|
|---|
| 29 | parameter Real LiqCp[6];
|
|---|
| 30 | parameter Real HOV[6];
|
|---|
| 31 | parameter Real VapCp[6];
|
|---|
| 32 | parameter Real LiqVis[6];
|
|---|
| 33 | parameter Real VapVis[6];
|
|---|
| 34 | parameter Real LiqK[6];
|
|---|
| 35 | parameter Real VapK[6];
|
|---|
| 36 | parameter Real Racketparam;
|
|---|
| 37 | end General_Properties;
|
|---|
| 38 |
|
|---|
| 39 | model Benzene
|
|---|
| 40 | extends General_Properties(SN = 125, name = "Benzene", Tc = 562.05, Pc = 4895000, Vc = 0.256, Cc = 0.268, Tb = 353.24, Tm = 278.68, TT = 278.68, TP = 4764.22, MW = 78.114, LVB = 0.08941, AF = 0.209, SP = 18700, DM = 0, SH = 49073013.1279, IGHF = 8.288E+07, GEF = 1.296E+08, AS = 269300, HFMP = 9866000, HOC = -3.136E+09, LiqDen = {105, 0.99938, 0.26348, 562.05, 0.27856, 0}, VP = {101, 88.368, -6712.9, -10.022, 0.000007694, 2}, LiqCp = {16, 111460, -1854.3, 22.399, -0.028936, 0.000028991}, HOV = {106, 4.881E+07, 0.61066, -0.25882, 0.032238, 0.022475}, VapCp = {16, 34010.24, -588.0978, 12.81777, -0.000197306, 5.142899E-08}, LiqVis = {101, -24.61, 1576.5, 2.1698, -0.0000051366, 2}, VapVis = {102, 3.1366E-08, 0.9675, 8.0285, -35.629, 0}, LiqK = {16, 0.049539, -177.97, 0.19475, -0.0073805, 0.0000027938}, VapK = {102, 0.0000049549, 1.4519, 154.14, 26202, 0}, Racketparam = 0.2696, UniquacR = 3.1878, UniquacQ = 2.4);
|
|---|
| 41 | end Benzene;
|
|---|
| 42 |
|
|---|
| 43 | model Toluene
|
|---|
| 44 | extends General_Properties(SN = 140, name = "Toluene", Tc = 591.75, Pc = 4108000, Vc = 0.316, Cc = 0.264, Tb = 383.79, Tm = 178.18, TT = 178.18, TP = 0.0475285, MW = 92.141, LVB = 0.10687, AF = 0.264, SP = 18250, DM = 1.2E-30, SH = 12079609.7184, IGHF = 5.017E+07, GEF = 1.222E+08, AS = 320990, HFMP = 6636000, HOC = -3.734E+09, LiqDen = {105, 0.89799, 0.27359, 591.75, 0.30006, 0}, VP = {101, 32.89891, -5013.81, -1.348918, -1.869928E-06, 2}, LiqCp = {16, 28291, 48.171, 10.912, 0.0020542, 8.7875E-07}, HOV = {106, 5.3752E+07, 0.50341, 0.24755, -0.72898, 0.37794}, VapCp = {16, 47225, -565.85, 12.856, 0.000005535, -1.998E-08}, LiqVis = {101, -152.84, 5644.6, 22.826, -0.000040987, 2}, VapVis = {102, 8.5581E-07, 0.49514, 307.82, 1891.6, 0}, LiqK = {16, -0.072922, -23.153, -1.0277, -0.0017074, 3.6787E-07}, VapK = {102, 0.000006541, 1.4227, 190.97, 21890, 0}, Racketparam = 0.2646, UniquacR = 3.9228, UniquacQ = 2.968);
|
|---|
| 45 | end Toluene;
|
|---|
| 46 |
|
|---|
| 47 | end Chemsep_Database;
|
|---|
| 48 |
|
|---|
| 49 | function Psat
|
|---|
| 50 | /*Returns vapor pressure at given temperature*/
|
|---|
| 51 | input Real VP[6] "from chemsep database";
|
|---|
| 52 | input Real T(unit = "K") "Temperature";
|
|---|
| 53 | output Real Vp(unit = "Pa") "Vapor pressure";
|
|---|
| 54 | algorithm
|
|---|
| 55 | Vp := exp(VP[2] + VP[3] / T + VP[4] * log(T) + VP[5] .* T .^ VP[6]);
|
|---|
| 56 | end Psat;
|
|---|
| 57 |
|
|---|
| 58 | function LiqCpId
|
|---|
| 59 | /*Calculates specific heat of liquid at given Temperature*/
|
|---|
| 60 | input Real LiqCp[6] "from chemsep database";
|
|---|
| 61 | input Real T(unit = "K") "Temperature";
|
|---|
| 62 | output Real Cp(unit = "J/mol") "Specific heat of liquid";
|
|---|
| 63 | algorithm
|
|---|
| 64 | Cp := (LiqCp[2] + exp(LiqCp[3] / T + LiqCp[4] + LiqCp[5] * T + LiqCp[6] * T ^ 2)) / 1000;
|
|---|
| 65 | end LiqCpId;
|
|---|
| 66 |
|
|---|
| 67 |
|
|---|
| 68 | function VapCpId
|
|---|
| 69 | /*Calculates Vapor Specific Heat*/
|
|---|
| 70 | input Real VapCp[6] "from chemsep database";
|
|---|
| 71 | input Real T(unit = "K") "Temperature";
|
|---|
| 72 | output Real Cp(unit = "J/mol.K") "specific heat";
|
|---|
| 73 | algorithm
|
|---|
| 74 | Cp := (VapCp[2] + exp(VapCp[3] / T + VapCp[4] + VapCp[5] * T + VapCp[6] * T ^ 2)) / 1000;
|
|---|
| 75 | end VapCpId;
|
|---|
| 76 |
|
|---|
| 77 | function HV
|
|---|
| 78 | /*Returns Heat of Vaporization*/
|
|---|
| 79 | input Real HOV[6] "from chemsep database";
|
|---|
| 80 | input Real Tc(unit = "K") "Critical Temperature";
|
|---|
| 81 | input Real T(unit = "K") "Temperature";
|
|---|
| 82 | output Real Hv(unit = "J/mol") "Heat of Vaporization";
|
|---|
| 83 | protected
|
|---|
| 84 | Real Tr = T / Tc;
|
|---|
| 85 | algorithm
|
|---|
| 86 | Hv := HOV[2] * (1 - Tr) ^ (HOV[3] + HOV[4] * Tr + HOV[5] * Tr ^ 2 + HOV[6] * Tr ^ 3) / 1000;
|
|---|
| 87 | end HV;
|
|---|
| 88 |
|
|---|
| 89 |
|
|---|
| 90 |
|
|---|
| 91 |
|
|---|
| 92 | function HLiqId
|
|---|
| 93 | /* Calculates Enthalpy of Ideal Liquid*/
|
|---|
| 94 | input Real SH(unit = "J/kmol") "from chemsep database std. Heat of formation";
|
|---|
| 95 | input Real VapCp[6] "from chemsep database";
|
|---|
| 96 | input Real HOV[6] "from chemsep database";
|
|---|
| 97 | input Real Tc "critical temp, from chemsep database";
|
|---|
| 98 | input Real T(unit = "K") "Temperature";
|
|---|
| 99 | output Real Ent(unit = "J/mol") "Molar Enthalpy";
|
|---|
| 100 | algorithm
|
|---|
| 101 | Ent := HVapId(SH, VapCp, HOV, Tc, T) - HV(HOV, Tc, T);
|
|---|
| 102 | end HLiqId;
|
|---|
| 103 |
|
|---|
| 104 |
|
|---|
| 105 |
|
|---|
| 106 |
|
|---|
| 107 |
|
|---|
| 108 |
|
|---|
| 109 |
|
|---|
| 110 | function HVapId
|
|---|
| 111 | /* Calculates enthalpy of ideal vapor */
|
|---|
| 112 | input Real SH(unit = "J/kmol") "from chemsep database std. Heat of formation";
|
|---|
| 113 | input Real VapCp[6] "from chemsep database";
|
|---|
| 114 | input Real HOV[6] "from chemsep database";
|
|---|
| 115 | input Real Tc "critical temp, from chemsep database";
|
|---|
| 116 | input Real T(unit = "K") "Temperature";
|
|---|
| 117 | output Real Ent(unit = "J/mol") "Molar Enthalpy";
|
|---|
| 118 | protected
|
|---|
| 119 | Real Temp = 298.15;
|
|---|
| 120 | algorithm
|
|---|
| 121 | Ent := 0;
|
|---|
| 122 | if T > 298.15 then
|
|---|
| 123 | while Temp < T loop
|
|---|
| 124 | Ent := Ent + VapCpId(VapCp, Temp) * 0.01;
|
|---|
| 125 | Temp := Temp + 0.01;
|
|---|
| 126 | end while;
|
|---|
| 127 | Ent := Ent;
|
|---|
| 128 | else
|
|---|
| 129 | while Temp > T loop
|
|---|
| 130 | Ent := Ent + VapCpId(VapCp, Temp) * 0.01;
|
|---|
| 131 | Temp := Temp - 0.01;
|
|---|
| 132 | end while;
|
|---|
| 133 | Ent := -Ent;
|
|---|
| 134 | end if;
|
|---|
| 135 | end HVapId;
|
|---|
| 136 |
|
|---|
| 137 | model Raoults_Law
|
|---|
| 138 | import Simulator.Files.Thermodynamic_Functions.*;
|
|---|
| 139 | Real K[NOC](each min = 0), resMolSpHeat[3], resMolEnth[3], resMolEntr[3];
|
|---|
| 140 | equation
|
|---|
| 141 | for i in 1:NOC loop
|
|---|
| 142 | K[i] = Psat(comp[i].VP, T) / P;
|
|---|
| 143 | end for;
|
|---|
| 144 | resMolSpHeat[:] = zeros(3);
|
|---|
| 145 | resMolEnth[:] = zeros(3);
|
|---|
| 146 | resMolEntr = zeros(3);
|
|---|
| 147 | end Raoults_Law;
|
|---|
| 148 |
|
|---|
| 149 | package Connection
|
|---|
| 150 | connector matConn
|
|---|
| 151 | Real P, T, mixMolFlo, mixMolEnth, mixMolEntr, mixMolFrac[connNOC](each min = 0, each max = 1), vapPhasMolFrac(min = 0, max = 1);
|
|---|
| 152 | parameter Integer connNOC;
|
|---|
| 153 | annotation(Icon(coordinateSystem(initialScale = 0.1), graphics = {Rectangle(fillColor = {175, 175, 175}, fillPattern = FillPattern.Solid, extent = {{-100, 100}, {100, -100}})}));
|
|---|
| 154 | end matConn;
|
|---|
| 155 |
|
|---|
| 156 |
|
|---|
| 157 | connector enConn
|
|---|
| 158 | Real enFlo;
|
|---|
| 159 | annotation(Icon(coordinateSystem(initialScale = 0.1), graphics = {Rectangle(fillColor = {255, 255, 33}, fillPattern = FillPattern.Solid, extent = {{-100, 100}, {100, -100}})}));
|
|---|
| 160 | end enConn;
|
|---|
| 161 |
|
|---|
| 162 |
|
|---|
| 163 |
|
|---|
| 164 | connector trayConn
|
|---|
| 165 | Real mixMolFlo, mixMolEnth, mixMolFrac[connNOC](each min = 0, each max = 1);
|
|---|
| 166 | parameter Integer connNOC;
|
|---|
| 167 | annotation(Icon(coordinateSystem(initialScale = 0.1), graphics = {Rectangle(fillColor = {8, 184, 211}, fillPattern = FillPattern.Solid, extent = {{-100, 100}, {100, -100}})}));
|
|---|
| 168 | end trayConn;
|
|---|
| 169 |
|
|---|
| 170 | end Connection;
|
|---|
| 171 |
|
|---|
| 172 | model Condensor1
|
|---|
| 173 | extends Raoults_Law;
|
|---|
| 174 | parameter Integer NOC = 2;
|
|---|
| 175 | parameter Chemsep_Database.General_Properties comp[NOC];
|
|---|
| 176 | Real P, T;
|
|---|
| 177 | Real feedMolFlo(min = 0), sideDrawMolFlo(min = 0), inVapMolFlo(min = 0), outLiqMolFlo(min = 0), feedMolFrac[NOC](each min = 0, each max = 1), sideDrawMolFrac[NOC](each min = 0 , each max = 1), inVapCompMolFrac[NOC](each min = 0, each max = 1), outLiqCompMolFrac[NOC](each min = 0, each max = 1), feedMolEnth, inVapMolEnth, outLiqMolEnth, outVapCompMolEnth[NOC], outLiqCompMolEnth[NOC], heatLoad, sideDrawMolEnth;
|
|---|
| 178 |
|
|---|
| 179 | parameter String condType"Partial or Total";
|
|---|
| 180 | Connection.matConn feed(connNOC = NOC) annotation(
|
|---|
| 181 | Placement(visible = true, transformation(origin = {-100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {-100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 182 | Connection.matConn side_draw(connNOC = NOC) annotation(
|
|---|
| 183 | Placement(visible = true, transformation(origin = {100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 184 | Connection.trayConn liquid_outlet(connNOC = NOC) annotation(
|
|---|
| 185 | Placement(visible = true, transformation(origin = {-50, -40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {-50, -40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 186 | Connection.trayConn vapor_inlet(connNOC = NOC) annotation(
|
|---|
| 187 | Placement(visible = true, transformation(origin = {50, -40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {50, -40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 188 | Connection.enConn heat_load annotation(
|
|---|
| 189 | Placement(visible = true, transformation(origin = {100, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {100, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 190 | equation
|
|---|
| 191 | //connector equation
|
|---|
| 192 | feed.mixMolFrac = feedMolFrac;
|
|---|
| 193 | feed.mixMolEnth = feedMolEnth;
|
|---|
| 194 | feed.mixMolFlo = feedMolFlo;
|
|---|
| 195 |
|
|---|
| 196 | side_draw.P = P;
|
|---|
| 197 | side_draw.T = T;
|
|---|
| 198 | side_draw.mixMolFrac = sideDrawMolFrac;
|
|---|
| 199 | side_draw.mixMolFlo = sideDrawMolFlo;
|
|---|
| 200 | side_draw.mixMolEnth = sideDrawMolEnth;
|
|---|
| 201 |
|
|---|
| 202 | liquid_outlet.mixMolFlo = outLiqMolFlo;
|
|---|
| 203 | liquid_outlet.mixMolEnth = outLiqMolEnth;
|
|---|
| 204 | liquid_outlet.mixMolFrac[:] = outLiqCompMolFrac[:];
|
|---|
| 205 |
|
|---|
| 206 | vapor_inlet.mixMolFlo = inVapMolFlo;
|
|---|
| 207 | vapor_inlet.mixMolEnth = inVapMolEnth;
|
|---|
| 208 | vapor_inlet.mixMolFrac[:] = inVapCompMolFrac[:];
|
|---|
| 209 |
|
|---|
| 210 | heat_load.enFlo = heatLoad;
|
|---|
| 211 | //molar balance
|
|---|
| 212 | //feedMolFlo + inVapMolFlo = sideDrawMolFlo + outLiqMolFlo;
|
|---|
| 213 | feedMolFlo .* feedMolFrac[:] + inVapMolFlo .* inVapCompMolFrac[:] = sideDrawMolFlo .* sideDrawMolFrac[:] + outLiqMolFlo .* outLiqCompMolFrac[:];
|
|---|
| 214 | //equillibrium
|
|---|
| 215 | if (condType == "Partial") then
|
|---|
| 216 | sideDrawMolFrac[:] = K[:] .* outLiqCompMolFrac[:];
|
|---|
| 217 | sideDrawMolEnth = sum(sideDrawMolFrac[:] .* outVapCompMolEnth[:]) + resMolEnth[3];
|
|---|
| 218 | elseif (condType == "Total") then
|
|---|
| 219 | sideDrawMolFrac[:] = outLiqCompMolFrac[:];
|
|---|
| 220 | sideDrawMolEnth = sum(sideDrawMolFrac[:] .* outLiqCompMolEnth[:]) + resMolEnth[2];
|
|---|
| 221 | end if;
|
|---|
| 222 | //summation equation
|
|---|
| 223 | sum(outLiqCompMolFrac[:]) = 1;
|
|---|
| 224 | //sum(sideDrawMolFrac[:]) = 1;
|
|---|
| 225 | // Enthalpy balance
|
|---|
| 226 | feedMolFlo * feedMolEnth + inVapMolFlo * inVapMolEnth = sideDrawMolFlo * sideDrawMolEnth + outLiqMolFlo * outLiqMolEnth + heatLoad;
|
|---|
| 227 |
|
|---|
| 228 | //enthalpy calculation
|
|---|
| 229 | for i in 1:NOC loop
|
|---|
| 230 | outLiqCompMolEnth[i] = HLiqId(comp[i].SH, comp[i].VapCp, comp[i].HOV, comp[i].Tc, T);
|
|---|
| 231 | outVapCompMolEnth[i] = HVapId(comp[i].SH, comp[i].VapCp, comp[i].HOV, comp[i].Tc, T);
|
|---|
| 232 | end for;
|
|---|
| 233 | outLiqMolEnth = sum(outLiqCompMolFrac[:] .* outLiqCompMolEnth[:]) + resMolEnth[2];
|
|---|
| 234 | // outVapMolEnth = sum(inVapCompMolFrac[:] .* outVapCompMolEnth[:]) + resMolEnth[3];
|
|---|
| 235 |
|
|---|
| 236 |
|
|---|
| 237 |
|
|---|
| 238 |
|
|---|
| 239 |
|
|---|
| 240 | annotation(
|
|---|
| 241 | Diagram(coordinateSystem(extent = {{-100, -40}, {100, 40}})),
|
|---|
| 242 | Icon(coordinateSystem(extent = {{-100, -40}, {100, 40}})),
|
|---|
| 243 | __OpenModelica_commandLineOptions = "");
|
|---|
| 244 | end Condensor1;
|
|---|
| 245 |
|
|---|
| 246 |
|
|---|
| 247 |
|
|---|
| 248 |
|
|---|
| 249 |
|
|---|
| 250 | model Reboiler1
|
|---|
| 251 | extends Raoults_Law;
|
|---|
| 252 | parameter Integer NOC = 2;
|
|---|
| 253 | parameter Chemsep_Database.General_Properties comp[NOC];
|
|---|
| 254 | Real P, T;
|
|---|
| 255 | Real feedMolFlo(min = 0), sideDrawMolFlo(min = 0), outVapMolFlo(min = 0), inLiqMolFlo(min = 0), feedMolFrac[NOC](each min = 0, each max = 1), sideDrawMolFrac[NOC](each min = 0, each max = 1), outVapCompMolFrac[NOC](each min = 0, each max = 1), inLiqCompMolFrac[NOC](each min = 0, each max = 1), feedMolEnth, outVapMolEnth, inLiqMolEnth, outVapCompMolEnth[NOC], sideDrawCompMolEnth[NOC], heatLoad, sideDrawMolEnth;
|
|---|
| 256 |
|
|---|
| 257 | Connection.matConn feed(connNOC = NOC) annotation(
|
|---|
| 258 | Placement(visible = true, transformation(origin = {-100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {-100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 259 | Connection.matConn side_draw(connNOC = NOC) annotation(
|
|---|
| 260 | Placement(visible = true, transformation(origin = {100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 261 | Connection.trayConn liquid_inlet(connNOC = NOC) annotation(
|
|---|
| 262 | Placement(visible = true, transformation(origin = {-50, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {-50, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 263 | Connection.trayConn vapor_outlet(connNOC = NOC) annotation(
|
|---|
| 264 | Placement(visible = true, transformation(origin = {50, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {50, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 265 | Connection.enConn heat_load annotation(
|
|---|
| 266 | Placement(visible = true, transformation(origin = {100, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {100, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 267 | equation
|
|---|
| 268 | //connector equation
|
|---|
| 269 | feed.mixMolFrac = feedMolFrac;
|
|---|
| 270 | feed.mixMolEnth = feedMolEnth;
|
|---|
| 271 | feed.mixMolFlo = feedMolFlo;
|
|---|
| 272 |
|
|---|
| 273 | side_draw.P = P;
|
|---|
| 274 | side_draw.T = T;
|
|---|
| 275 | side_draw.mixMolFrac = sideDrawMolFrac;
|
|---|
| 276 | side_draw.mixMolFlo = sideDrawMolFlo;
|
|---|
| 277 | side_draw.mixMolEnth = sideDrawMolEnth;
|
|---|
| 278 |
|
|---|
| 279 | liquid_inlet.mixMolFlo = inLiqMolFlo;
|
|---|
| 280 | liquid_inlet.mixMolEnth = inLiqMolEnth;
|
|---|
| 281 | liquid_inlet.mixMolFrac[:] = inLiqCompMolFrac[:];
|
|---|
| 282 |
|
|---|
| 283 | vapor_outlet.mixMolFlo = outVapMolFlo;
|
|---|
| 284 | vapor_outlet.mixMolEnth = outVapMolEnth;
|
|---|
| 285 | vapor_outlet.mixMolFrac[:] = outVapCompMolFrac[:];
|
|---|
| 286 |
|
|---|
| 287 | heat_load.enFlo = heatLoad;
|
|---|
| 288 | //molar balance
|
|---|
| 289 | feedMolFlo + inLiqMolFlo = sideDrawMolFlo + outVapMolFlo;
|
|---|
| 290 |
|
|---|
| 291 | // feedMolFlo .* feedMolFrac[:] + inLiqMolFlo .* inLiqCompMolFrac[:] = sideDrawMolFlo .* sideDrawMolFrac[:] + outVapMolFlo .* outVapCompMolFrac[:];
|
|---|
| 292 |
|
|---|
| 293 | //equillibrium
|
|---|
| 294 | outVapCompMolFrac[:] = K[:] .* sideDrawMolFrac[:];
|
|---|
| 295 | //summation equation
|
|---|
| 296 | sum(outVapCompMolFrac[:]) = 1;
|
|---|
| 297 | sum(sideDrawMolFrac[:]) = 1;
|
|---|
| 298 | // Enthalpy balance
|
|---|
| 299 | feedMolFlo * feedMolEnth + inLiqMolFlo * inLiqMolEnth = sideDrawMolFlo * sideDrawMolEnth + outVapMolFlo * outVapMolEnth + heatLoad;
|
|---|
| 300 | //enthalpy calculation
|
|---|
| 301 | for i in 1:NOC loop
|
|---|
| 302 | sideDrawCompMolEnth[i] =HLiqId(comp[i].SH, comp[i].VapCp, comp[i].HOV, comp[i].Tc, T);
|
|---|
| 303 | outVapCompMolEnth[i] = HVapId(comp[i].SH, comp[i].VapCp, comp[i].HOV, comp[i].Tc, T);
|
|---|
| 304 | end for;
|
|---|
| 305 | sideDrawMolEnth = sum(sideDrawMolFrac[:] .* sideDrawCompMolEnth[:]) + resMolEnth[2];
|
|---|
| 306 | outVapMolEnth = sum(outVapCompMolFrac[:] .* outVapCompMolEnth[:]) + resMolEnth[3];
|
|---|
| 307 | annotation(
|
|---|
| 308 | Diagram(coordinateSystem(extent = {{-100, -40}, {100, 40}})),
|
|---|
| 309 | Icon(coordinateSystem(extent = {{-100, -40}, {100, 40}})),
|
|---|
| 310 | __OpenModelica_commandLineOptions = "");
|
|---|
| 311 | end Reboiler1;
|
|---|
| 312 |
|
|---|
| 313 |
|
|---|
| 314 |
|
|---|
| 315 |
|
|---|
| 316 |
|
|---|
| 317 | model distillTray1
|
|---|
| 318 | extends Raoults_Law;
|
|---|
| 319 | parameter Integer NOC = 2;
|
|---|
| 320 | parameter Chemsep_Database.General_Properties comp[NOC];
|
|---|
| 321 | Real P, T(start = (min(comp[:].Tb) + max(comp[:].Tb)) / NOC);
|
|---|
| 322 | Real feedMolFlo(min = 0), sideDrawMolFlo(min = 0), vapMolFlo[2](each min = 0), liqMolFlo[2](each min = 0), feedMolFrac[NOC](each min = 0, each max = 1), sideDrawMolFrac[NOC](each min = 0, each max = 1), vapCompMolFrac[2, NOC](each min = 0, each max = 1), liqCompMolFrac[2, NOC](each min = 0, each max = 1), feedMolEnth, vapMolEnth[2], liqMolEnth[2], outVapCompMolEnth[NOC], outLiqCompMolEnth[NOC], heatLoad, sideDrawMolEnth;
|
|---|
| 323 | String sideDrawType(start = "Null");
|
|---|
| 324 | //L or V
|
|---|
| 325 | Connection.matConn feed(connNOC = NOC) annotation(
|
|---|
| 326 | Placement(visible = true, transformation(origin = {-100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {-100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 327 | Connection.matConn side_draw(connNOC = NOC) annotation(
|
|---|
| 328 | Placement(visible = true, transformation(origin = {100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {100, 0}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 329 | Connection.trayConn liquid_inlet(connNOC = NOC) annotation(
|
|---|
| 330 | Placement(visible = true, transformation(origin = {-50, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {-50, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 331 | Connection.trayConn liquid_outlet(connNOC = NOC) annotation(
|
|---|
| 332 | Placement(visible = true, transformation(origin = {-50, -40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {-50, -40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 333 | Connection.trayConn vapor_outlet(connNOC = NOC) annotation(
|
|---|
| 334 | Placement(visible = true, transformation(origin = {50, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {50, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 335 | Connection.trayConn vapor_inlet(connNOC = NOC) annotation(
|
|---|
| 336 | Placement(visible = true, transformation(origin = {50, -40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {50, -40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 337 | Connection.enConn heat_load annotation(
|
|---|
| 338 | Placement(visible = true, transformation(origin = {100, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0), iconTransformation(origin = {100, 40}, extent = {{-10, -10}, {10, 10}}, rotation = 0)));
|
|---|
| 339 | equation
|
|---|
| 340 | //connector equation
|
|---|
| 341 | feed.mixMolFrac = feedMolFrac;
|
|---|
| 342 | feed.mixMolEnth = feedMolEnth;
|
|---|
| 343 | feed.mixMolFlo = feedMolFlo;
|
|---|
| 344 |
|
|---|
| 345 | side_draw.P = P;
|
|---|
| 346 | side_draw.T = T;
|
|---|
| 347 | side_draw.mixMolFrac = sideDrawMolFrac;
|
|---|
| 348 | side_draw.mixMolFlo = sideDrawMolFlo;
|
|---|
| 349 | side_draw.mixMolEnth = sideDrawMolEnth;
|
|---|
| 350 |
|
|---|
| 351 | liquid_inlet.mixMolFlo = liqMolFlo[1];
|
|---|
| 352 | liquid_inlet.mixMolEnth = liqMolEnth[1];
|
|---|
| 353 | liquid_inlet.mixMolFrac[:] = liqCompMolFrac[1, :];
|
|---|
| 354 |
|
|---|
| 355 | liquid_outlet.mixMolFlo = liqMolFlo[2];
|
|---|
| 356 | liquid_outlet.mixMolEnth = liqMolEnth[2];
|
|---|
| 357 | liquid_outlet.mixMolFrac[:] = liqCompMolFrac[2, :];
|
|---|
| 358 |
|
|---|
| 359 | vapor_inlet.mixMolFlo = vapMolFlo[1];
|
|---|
| 360 | vapor_inlet.mixMolEnth = vapMolEnth[1];
|
|---|
| 361 | vapor_inlet.mixMolFrac[:] = vapCompMolFrac[1, :];
|
|---|
| 362 |
|
|---|
| 363 | vapor_outlet.mixMolFlo = vapMolFlo[2];
|
|---|
| 364 | vapor_outlet.mixMolEnth = vapMolEnth[2];
|
|---|
| 365 | vapor_outlet.mixMolFrac[:] = vapCompMolFrac[2, :];
|
|---|
| 366 |
|
|---|
| 367 | heat_load.enFlo = heatLoad;
|
|---|
| 368 | //molar balance
|
|---|
| 369 | //feedMolFlo + vapMolFlo[1] + liqMolFlo[1] = sideDrawMolFlo + vapMolFlo[2] + liqMolFlo[2];
|
|---|
| 370 | feedMolFlo .* feedMolFrac[:] + vapMolFlo[1] .* vapCompMolFrac[1, :] + liqMolFlo[1] .* liqCompMolFrac[1, :] = sideDrawMolFlo .* sideDrawMolFrac[:] + vapMolFlo[2] .* vapCompMolFrac[2, :] + liqMolFlo[2] .* liqCompMolFrac[2, :];
|
|---|
| 371 | //equillibrium
|
|---|
| 372 | vapCompMolFrac[2, :] = K[:] .* liqCompMolFrac[2, :];
|
|---|
| 373 | //summation equation
|
|---|
| 374 | sum(liqCompMolFrac[2, :]) = 1;
|
|---|
| 375 | sum(vapCompMolFrac[2, :]) = 1;
|
|---|
| 376 | // Enthalpy balance
|
|---|
| 377 | feedMolFlo * feedMolEnth + vapMolFlo[1] * vapMolEnth[1] + liqMolFlo[1] * liqMolEnth[1] = sideDrawMolFlo * sideDrawMolEnth + vapMolFlo[2] * vapMolEnth[2] + liqMolFlo[2] * liqMolEnth[2] + heatLoad;
|
|---|
| 378 | //enthalpy calculation
|
|---|
| 379 | for i in 1:NOC loop
|
|---|
| 380 | outLiqCompMolEnth[i] = HLiqId(comp[i].SH, comp[i].VapCp, comp[i].HOV, comp[i].Tc, T);
|
|---|
| 381 | outVapCompMolEnth[i] = HVapId(comp[i].SH, comp[i].VapCp, comp[i].HOV, comp[i].Tc, T);
|
|---|
| 382 | end for;
|
|---|
| 383 | liqMolEnth[2] = sum(liqCompMolFrac[2, :] .* outLiqCompMolEnth[:]) + resMolEnth[2];
|
|---|
| 384 | vapMolEnth[2] = sum(vapCompMolFrac[2, :] .* outVapCompMolEnth[:]) + resMolEnth[3];
|
|---|
| 385 | //sidedraw calculation
|
|---|
| 386 | if sideDrawType == "L" then
|
|---|
| 387 | sideDrawMolFrac[:] = liqCompMolFrac[2, :];
|
|---|
| 388 | elseif sideDrawType == "V" then
|
|---|
| 389 | sideDrawMolFrac[:] = vapCompMolFrac[2, :];
|
|---|
| 390 | else
|
|---|
| 391 | sideDrawMolFrac[:] = zeros(NOC);
|
|---|
| 392 | end if;
|
|---|
| 393 | annotation(
|
|---|
| 394 | Diagram(coordinateSystem(extent = {{-100, -40}, {100, 40}})),
|
|---|
| 395 | Icon(coordinateSystem(extent = {{-100, -40}, {100, 40}})),
|
|---|
| 396 | __OpenModelica_commandLineOptions = "");
|
|---|
| 397 | end distillTray1;
|
|---|
| 398 |
|
|---|
| 399 |
|
|---|
| 400 |
|
|---|
| 401 |
|
|---|
| 402 | model column1
|
|---|
| 403 | import data = Post.Chemsep_Database;
|
|---|
| 404 | //instantiation of chemsep database
|
|---|
| 405 | parameter data.Benzene benz;
|
|---|
| 406 | parameter data.Toluene tol;
|
|---|
| 407 | parameter Integer NOC = 2;
|
|---|
| 408 | parameter data.General_Properties comp[NOC] = {benz, tol};
|
|---|
| 409 | parameter String condType = "Total";
|
|---|
| 410 | parameter Integer noOfStages = 3, noOfFeeds = 1, feedStages[noOfFeeds] = {1}, noOfSideDraws = 0, sideDrawStages[noOfSideDraws], noOfHeatLoads = 1, heatLoadStages[noOfHeatLoads] = {1};
|
|---|
| 411 |
|
|---|
| 412 | distillTray1 tray[noOfStages - 2](each NOC = NOC,each comp = comp, T(start = 370), liquid_outlet.mixMolFlo(start = 81.3864), vapor_outlet.mixMolFlo(start = 100.999));
|
|---|
| 413 | Condensor1 condensor(NOC = NOC, comp = comp, condType = condType, liquid_outlet.mixMolFlo(start = 50.999));
|
|---|
| 414 | Reboiler1 reboiler(NOC = NOC, comp = comp, vapor_outlet.mixMolFlo(start = 31.3864));
|
|---|
| 415 |
|
|---|
| 416 | //Connection.matConn feed[noOfFeeds](each connNOC = NOC);
|
|---|
| 417 | //Connection.enConn heat_load[noOfHeatLoads];
|
|---|
| 418 |
|
|---|
| 419 | equation
|
|---|
| 420 | //connector equation
|
|---|
| 421 | connect(tray[1].liquid_inlet, condensor.liquid_outlet);
|
|---|
| 422 | connect(tray[1].vapor_outlet, condensor.vapor_inlet);
|
|---|
| 423 | connect(tray[noOfStages - 2].liquid_outlet, reboiler.liquid_inlet);
|
|---|
| 424 | connect(tray[noOfStages - 2].vapor_inlet, reboiler.vapor_outlet);
|
|---|
| 425 | //tray equation
|
|---|
| 426 | tray[1].sideDrawType = "Null";
|
|---|
| 427 | tray[1].heat_load.enFlo = 0;
|
|---|
| 428 | tray[1].P = 101325;
|
|---|
| 429 | tray[1].feed.mixMolFlo = 100;
|
|---|
| 430 | tray[1].feed.mixMolEnth = -2584.65;
|
|---|
| 431 | tray[1].feed.mixMolFrac = {0.5, 0.5};
|
|---|
| 432 | tray[1].side_draw.mixMolFlo = 0;
|
|---|
| 433 | tray[1].side_draw.mixMolEnth = 0;
|
|---|
| 434 | tray[1].side_draw.mixMolEntr = 0;
|
|---|
| 435 | tray[1].side_draw.vapPhasMolFrac = 0;
|
|---|
| 436 |
|
|---|
| 437 | //condensor equation
|
|---|
| 438 | condensor.P = 101325;
|
|---|
| 439 | condensor.side_draw.mixMolFlo = 50;
|
|---|
| 440 | condensor.side_draw.T = 351.1855;
|
|---|
| 441 | condensor.side_draw.mixMolEntr = 0;
|
|---|
| 442 | condensor.side_draw.vapPhasMolFrac = 0;
|
|---|
| 443 |
|
|---|
| 444 |
|
|---|
| 445 | //Reboiler equation
|
|---|
| 446 | reboiler.P = 101325;
|
|---|
| 447 | reboiler.side_draw.mixMolFlo = 50;
|
|---|
| 448 | reboiler.side_draw.T = 370.076;
|
|---|
| 449 | reboiler.side_draw.mixMolEntr = 0;
|
|---|
| 450 | reboiler.side_draw.vapPhasMolFrac = 0;
|
|---|
| 451 |
|
|---|
| 452 |
|
|---|
| 453 | algorithm
|
|---|
| 454 | //feed equation
|
|---|
| 455 | for i in 1:(noOfStages - 2) loop
|
|---|
| 456 | for j in 1:noOfFeeds loop
|
|---|
| 457 | if (feedStages[j] == i) then
|
|---|
| 458 | tray[i].feed.P := 101325;
|
|---|
| 459 | tray[i].feed.T := 370;
|
|---|
| 460 | tray[i].feed.mixMolEntr := 0;
|
|---|
| 461 | tray[i].feed.vapPhasMolFrac := 0;
|
|---|
| 462 | break;
|
|---|
| 463 | else
|
|---|
| 464 | tray[i].feed.P := 0;
|
|---|
| 465 | tray[i].feed.T := 0;
|
|---|
| 466 | tray[i].feed.mixMolEntr := 0;
|
|---|
| 467 | tray[i].feed.vapPhasMolFrac := 0;
|
|---|
| 468 | end if;
|
|---|
| 469 | end for;
|
|---|
| 470 | end for;
|
|---|
| 471 |
|
|---|
| 472 | for j in 1:noOfFeeds loop
|
|---|
| 473 | if (feedStages[j] == (noOfStages - 1)) then
|
|---|
| 474 | reboiler.feed.P := 0;
|
|---|
| 475 | reboiler.feed.T := 0;
|
|---|
| 476 | reboiler.feed.mixMolFlo := 0;
|
|---|
| 477 | reboiler.feed.mixMolEnth := 0;
|
|---|
| 478 | reboiler.feed.mixMolEntr := 0;
|
|---|
| 479 | // reboiler.feed.mixMolFrac[:] := zeros(NOC);
|
|---|
| 480 | reboiler.feed.vapPhasMolFrac := 0;
|
|---|
| 481 | break;
|
|---|
| 482 | else
|
|---|
| 483 | reboiler.feed.P := 0;
|
|---|
| 484 | reboiler.feed.T := 0;
|
|---|
| 485 | reboiler.feed.mixMolFlo := 0;
|
|---|
| 486 | reboiler.feed.mixMolEnth := 0;
|
|---|
| 487 | reboiler.feed.mixMolEntr := 0;
|
|---|
| 488 | // reboiler.feed.mixMolFrac[:] := zeros(NOC);
|
|---|
| 489 | reboiler.feed.vapPhasMolFrac := 0;
|
|---|
| 490 | end if;
|
|---|
| 491 | end for;
|
|---|
| 492 |
|
|---|
| 493 | for j in 1:noOfFeeds loop
|
|---|
| 494 | if (feedStages[j] == noOfStages) then
|
|---|
| 495 | condensor.feed.P := 0;
|
|---|
| 496 | condensor.feed.T := 0;
|
|---|
| 497 | condensor.feed.mixMolFlo := 0;
|
|---|
| 498 | condensor.feed.mixMolEnth := 0;
|
|---|
| 499 | condensor.feed.mixMolEntr := 0;
|
|---|
| 500 | condensor.feed.mixMolFrac[:] := zeros(NOC);
|
|---|
| 501 | condensor.feed.vapPhasMolFrac := 0;
|
|---|
| 502 | break;
|
|---|
| 503 | else
|
|---|
| 504 | condensor.feed.P := 0;
|
|---|
| 505 | condensor.feed.T := 0;
|
|---|
| 506 | condensor.feed.mixMolFlo := 0;
|
|---|
| 507 | condensor.feed.mixMolEnth := 0;
|
|---|
| 508 | condensor.feed.mixMolEntr := 0;
|
|---|
| 509 | condensor.feed.mixMolFrac[:] := zeros(NOC);
|
|---|
| 510 | condensor.feed.vapPhasMolFrac := 0;
|
|---|
| 511 | end if;
|
|---|
| 512 | end for;
|
|---|
| 513 |
|
|---|
| 514 | reboiler.feed.mixMolFrac := {0, 0};
|
|---|
| 515 | //condensor.feed.mixMolFrac := {0, 0};
|
|---|
| 516 |
|
|---|
| 517 | //Condensor and reboiler feed.mixMolFrac is creating a problem. If I directly giving value in algorithm it works. It gives error when ran inside if-else statement.
|
|---|
| 518 | end column1;
|
|---|
| 519 |
|
|---|
| 520 |
|
|---|
| 521 |
|
|---|
| 522 |
|
|---|
| 523 |
|
|---|
| 524 |
|
|---|
| 525 | end Post;
|
|---|